US3862028A - Flotation-beneficiation of phosphate ores - Google Patents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/08—Subsequent treatment of concentrated product
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- This invention relates to an improvement in the flotationbeneficiation of phosphate ores containing a substantial quantity of siliceous materials.
- Crude ores are first comminuted, then subjected to various physical methods of concentration to separate valuable minerals from the waste materials (i.e., gangue) which usually consist of clay, silicas, and other minerals having little or no value.
- waste materials i.e., gangue
- Much of the gangue can be removed by water washing, screening, and gravity separations, but in most beneficiation processes of siliceous ores, the final and most important step is flotation.
- Phosphate ore deposits are subsurface pockets of phosphate ore (matrix) which consist mainly of about one-third each of sand, clay. and calcium fluorapatite.
- the phosphate contained in the matrix ranges in size from At-inch pebbles" down to minus 150 mesh particles and generally is in the form of discrete grains with rather small amounts of included quartz sand.
- the free silica is normally mainly minus 20 mesh.
- the type and consistency of the clay varies and is mixed but generally is distributed throughout the matrix.
- Pebble rock removed by screening varies in grade from ore body to ore body but generally ranges from 65-75 percent BPL (bone phosphate of lime or tricalcium phosphate). Constituting about I percent of the matrix, pebble phosphate is marketable without further processing.
- BPL bone phosphate of lime or tricalcium phosphate
- the balance of the material remaining from the matrix is chiefly fluorapatite and sand of varying and similar particle sizes which precludes separation by physical means.
- An elegant and now widely used method of separating the two involves twostage flotation. In the first flotation stage, flotation reagents such as tall oil fatty acids (anionic collectors or frothers), and No. fuel oil (activator or extender to aid in froth control) are used to float phosphate from the sand tailings (nonfloat).
- Anionic flotation of phosphates is not specific, especially under conditions providing high BPL recovery required by process economics, and the float concentrate normally contains I()-I5 percent silica.
- the second flotation stage further reduces the amount of silica by treating the float concentrate from the first stage with a mineral acid to remove the flotation reagents, and relloating the concentrate in the presence of an amine collector.
- the final float concentrate from this two-step flotation usually contains over 75 percent BPL, less than 5 percent acid insolubles (silica), and a BPL recovery of from about 90 to 95 percent.
- Dual flotation in the manner described is obviously more expensive than single-stage flotation because of additional equipment, reagents, etc. It is the method of choice, however, since single-stage flotation cannot provide marketable grade phosphate concomitant with satisfactory BPL recovery. Preventing complete separation with good BPL recovery is the lack of specificity of the anionic collector for phosphate particles. Search for a more specific collector or for a selective depressant for silica (e.g., U.S. Pat. Nos. 2,740,522 and 3,321,649) antedates development of the two-stage flotation with only limited success as evidenced by the continuing use of the twostage process in phosphate production.
- Graft polymers of starch and quaternary ammonium derivatives of aminoalkyl methacrylate have been shown to flocculate silica suspended in water, but settling times of at least one-half hour were required to remove from 45 to 85 percent of the silica from a 1 percent aqueous dispersion (U.S. Pat. No. 3,669,915).
- gamma irradiation is the preferred polymerization initiator and starch the preferred substrate. This combination is simple and usually results in clean, easy-to-recover products.
- Chemical initiators e.g., Ce, Fe -H and other irradiation initiators (e.g., electron, ultraviolet) are equivalent to gamma irradiation in the method, and any starch such as that from corn, rice, sorghum. etc. is an equivalent substrate to the wheat starch described in the examples.
- wheat starch is irradiated with a total dosage of 5.0
- the quaternary ammonium derivative of aminoalkyl methacrylate monomer which was selected as a representative example has the structure shown below:
- Example 7 Flotation studies on Florida phosphate ore were carried out in a Denver Laboratory flotation cell. Examples 3 through 6 indicate procedures valuable for determining the optimum conditions of parameters such as addition levels for flotation reagents (e.g., collectors, activators, extenders, or depressants), order of addition, and effects of additives on each other.
- the pret'erred conditions for the particular flotation system and phosphate ore discussed herein are elaborated in Example 7.
- the addition level for the graft polymers is from 0.025 to about 0.2 pound/ton. However, the preferred addition level is from 0.025 to 0.05 pound/ton.
- the preferred polymer content is from about 2.5 to percent by weight of poly(l) in st-g-poly(l) and from about 2 to 11 percent by weight poly(l) and 5 to percent by weight poly(lll) in st-g-poly(l-co-lll).
- EXAMPLE 1 Powdered wheat starch (100 g.; 9.8 percent moisture; 0.56 equivalent) was irradiated under a nitrogen atmosphere in a cobalt 60 source for 330 minutes at a dose rate of0.91 megarad/hour (total dosage 5.0 megarad) transferred to a reaction flask containing a nitrogen-prepurged aqueous solution of monomer (for reactions ofl, 475 ml. H O used; reaction with land 111, 550 ml. H O used). The reaction was allowed to proceed for 2 hours at 30 C. under a nitrogen atmosphere.
- the product was isolated by filtration after dilution of the reaction mixture with two volumes of isopropanol, washed successively with isopropanol and acetone, and dried 16 hours in vacuo at C.
- the products were analyzed for nitrogen, chlorine, and moisture. These values were used to calculate graft content and graft composition, Table I.
- This monomer, 2-hydr0xy-3-methacryloyloxypropyltrimethylammonium chloride, is to be known herein as l.
- the acrylamide comonomer is to be known as 111.
- the starch graft polymers will be designated as st-gpoly(l) and st-g-poly(l-eo-lll) according to the method described by Battaerd and Tregear, (irufr Poly mum. lnterscienee Publishers, New York, New York, pages l4-l6.
- EXAMPLE 5 Flotation studies were run as described in Example 3. except that the graft polymer from Run No. 5, Table 1, was added prior to the collector in various levels. The collector and activator were added at a 1.14-pound/ton level in each run. For analyses. see Table 5.
- EXAMPLE 7 Flotation studies were run as described in Example 3. Three different starch graft polymers were compared as silica depressants to two cationic starches and a wheat starch. Each was added prior to the addition of flotation reagents 1:1 mixture oftall oil fatty acids and oil fatty acids and No. 5 fuel oil and from 0.025 to 0.2 pound/ton of ore of a graft polymer comprised of a starch substrate onto which is grafted a member selected from the group consisting of a polymerized quaternary ammonium derivative of aminotrialkyl methacrylate and mixtures of a polymerized quaternary ammonium derivative of aminotrialkyl methacrylate with polyacrylamide; and b.
- graft polymer contains from about 2.5 to percent by weight of a polymerized quaternary ammonium derivative of aminotrialkyl methacrylate consisting of 2- No. 5 fuel oil each at the 1.14-pound/ton level), Table 15 hydroxy 3-methacwlwloxwmwltrimethylammonium chloride.
- a. froth floating phosphate ore in the presence of tall 3. The method described in claim I in which the graft polymer contains from about 2 to l 1 percent by weight of a polymerized quaternary ammonium derivative of aminotrialkyl methacrylate consisting of 2-hydroxy-3- methacryloyloxypropyltrimethylammonium chloride and from about 5 to 20 percent by weight polyacrylamide.
Abstract
An improved method of separating minerals from phosphate ores is described. The addition of silica depressants to flotation slurries substantially increases the efficiency of mineral separation and thereby reduces the number of flotation steps required to obtain a good yield of ore having the desired mineral concentration.
Description
United States Patent Jones et al.
FLOTATION-BENEFICIATION OF PHOSPHATE ORES Inventors: Duane A. Jones, Minneapolis,
Minn.; Wesley A. Jordan, Denver, Colo.
The United States of America as represented by the Secretary of Agriculture, Washington, DC.
Filed: Nov. 20, 1973 Appl. N0.: 417,645
Related U.S. Application Data C0ntinuation-in-part of Ser. No. 149,859, June 3, 1971, abandoned.
Assignee:
U.S. Cl. 209/166, 209/10 Int. Cl B03d 1/02 Field of Search 209/5, 166, 10; 252/61;
References Cited UNITED STATES PATENTS 4/1956 Aimone 209/166 Jan. 21, 1975 Woolery 209/166 X 3,321,649 5/1967 DeBenedictis... 209/166 X 3,575,868 4/1971 Galvin 2l0/54 X 3,635,857 l/l972 Restaino 210/54 X 3,669,915 6/1972 Jones 209/5 X Primary Examiner-Robert Halper Attorney, Agent, or FirmM. Howard Silverstein; Max D. Hensley; David G. McConnell 5 Claims, No Drawings FLOTATlON-BENEFICIATION OF PHOSPHATE ORES This is a continuation-in-part application of Ser. No.
149,859 now abandoned filed June 3, I971.
BACKGROUND OF THE INVENTION This invention relates to an improvement in the flotationbeneficiation of phosphate ores containing a substantial quantity of siliceous materials.
Crude ores are first comminuted, then subjected to various physical methods of concentration to separate valuable minerals from the waste materials (i.e., gangue) which usually consist of clay, silicas, and other minerals having little or no value.
Much of the gangue can be removed by water washing, screening, and gravity separations, but in most beneficiation processes of siliceous ores, the final and most important step is flotation.
Phosphate ore deposits, particularly those in Florida, are subsurface pockets of phosphate ore (matrix) which consist mainly of about one-third each of sand, clay. and calcium fluorapatite. The phosphate contained in the matrix ranges in size from At-inch pebbles" down to minus 150 mesh particles and generally is in the form of discrete grains with rather small amounts of included quartz sand. The free silica is normally mainly minus 20 mesh. The type and consistency of the clay varies and is mixed but generally is distributed throughout the matrix.
The nature of the phosphate pebble and the size of the silica lends the matrix to an effective beneflciation process which consists of the following main steps after mining of the ore:
1. Washing-to remove clay.
2. Screening-to remove +16 mesh pebble (generally relatively high-grade material).
3. Flotation -to recover I 6 to +150 mesh phosphate from silica and clay.
Pebble rock removed by screening varies in grade from ore body to ore body but generally ranges from 65-75 percent BPL (bone phosphate of lime or tricalcium phosphate). Constituting about I percent of the matrix, pebble phosphate is marketable without further processing.
The balance of the material remaining from the matrix is chiefly fluorapatite and sand of varying and similar particle sizes which precludes separation by physical means. An elegant and now widely used method of separating the two involves twostage flotation. In the first flotation stage, flotation reagents such as tall oil fatty acids (anionic collectors or frothers), and No. fuel oil (activator or extender to aid in froth control) are used to float phosphate from the sand tailings (nonfloat). Anionic flotation of phosphates is not specific, especially under conditions providing high BPL recovery required by process economics, and the float concentrate normally contains I()-I5 percent silica. The second flotation stage further reduces the amount of silica by treating the float concentrate from the first stage with a mineral acid to remove the flotation reagents, and relloating the concentrate in the presence of an amine collector. The final float concentrate from this two-step flotation usually contains over 75 percent BPL, less than 5 percent acid insolubles (silica), and a BPL recovery of from about 90 to 95 percent.
Dual flotation in the manner described is obviously more expensive than single-stage flotation because of additional equipment, reagents, etc. It is the method of choice, however, since single-stage flotation cannot provide marketable grade phosphate concomitant with satisfactory BPL recovery. Preventing complete separation with good BPL recovery is the lack of specificity of the anionic collector for phosphate particles. Search for a more specific collector or for a selective depressant for silica (e.g., U.S. Pat. Nos. 2,740,522 and 3,321,649) antedates development of the two-stage flotation with only limited success as evidenced by the continuing use of the twostage process in phosphate production.
It is the object of this invention to provide an improvement in the efficiency of the flotation process and thereby reduce the number of flotation steps.
In accordance with the above-stated object, we have discovered in a method of flotation-beneficiation of phosphate ores which normally includes the steps of:
a. floating the ore in the presence of flotation reagents;
b. collecting the first float;
c. removing the flotation reagents from the first float;
d. floating the first float in the presence of an amine collector; and
e. collecting the second float; an improvement by which flotation is accomplished in a single stage, comprising the steps of:
a. froth floating phosphate ore in the presence of flotation reagents and from 0.025 to 0.2 pound/ton of ore of a graft polymer comprised of a starch substrate onto which is grafted a member selected from the group consisting of a polymerized quaternary ammonium derivative of aminoalkyl methacrylate and mixtures of a polymerized quaternary ammonium derivative of aminoalkyl methacrylate with polyacrylamide; and
b. collecting, filtering, and drying the resulting float.
The potential importance of this discovery cannot be estimated precisely. However, a rough estimate can be determined assuming annual Florida pebble phosphate production volume of about 10 million tons. Approximately 7 million tons of this is produced by flotation processes which consume an estimated 35 million pounds of flotation reagents annually. Use of starch graft copolymer as described herein would replace approximately I5 million pounds of flotation reagent (specifically, sulfuric acid and amine collector) with a graft polymer consumption of 0.350.70 million pounds. This it should be noted pertains only to domestic phosphate production in Florida.
DETAILED DESCRIPTION OF THE INVENTION In a comprehensive review J. C. Arthur, .lr. describes the state of the art of graft polymerization onto polysaccharide backbones (Advances in Macromolecular Chemistry, Vol. 2, Academic Press, London and New York, I970). Celluloses. starches, modified starches, and starch derivatives are included in the list of polysaccharides used as substrates onto which many vinyltype monomers have been grafted. In most methods of producing graft polymers, the reaction is initiated by forming free radical sites on the substrate. This is accomplished with initiators such as ceric ion, ferrous ion-hydrogen peroxide, and irradiation.
Graft polymers of starch and quaternary ammonium derivatives of aminoalkyl methacrylate have been shown to flocculate silica suspended in water, but settling times of at least one-half hour were required to remove from 45 to 85 percent of the silica from a 1 percent aqueous dispersion (U.S. Pat. No. 3,669,915). We were surprised, therefore, when the instant compositions, used in the highly agitated conditions found in a flotation cell, provided float concentrates having BPL concentrations and recoveries sufficient to completely eliminate the necessity for the amine flotation step.
In preparing the instant compositions gamma irradiation is the preferred polymerization initiator and starch the preferred substrate. This combination is simple and usually results in clean, easy-to-recover products. Chemical initiators (e.g., Ce, Fe -H and other irradiation initiators (e.g., electron, ultraviolet) are equivalent to gamma irradiation in the method, and any starch such as that from corn, rice, sorghum. etc. is an equivalent substrate to the wheat starch described in the examples.
In the preferred embodiments (Example 1, infra),
wheat starch is irradiated with a total dosage of 5.0
megarad of gamma radiation with a cobalt 60 source. 1t has been previously determined that a dose of 5.0 megarad of gamma radiation gave the maximum concentration of trapped free radicals [Reyes et al., J. Polym. Sci. 23: 401-408 (1968)]. The irradiated starch, under a nitrogen atmosphere, is then brought in contact with a solution of monomer and allowed to react for times sufficient to obtain maximum grafting. Reaction temperatures of between 25-30 C. are preferred because higher temperatures cause the starch to swell and produce graft polymers that are difficult to recover.
The quaternary ammonium derivative of aminoalkyl methacrylate monomer which was selected as a representative example has the structure shown below:
a H I 0151- -o-cn H -CH -N-(ClL-Q 01 of a graft polymer containing less than 2 percent poly(l) and less than 5 percent poly(lll). This particular product (reaction No. 4, Table 1) contained chlorine and nitrogen at levels too low for accurate determination of polymer content.
Flotation studies on Florida phosphate ore were carried out in a Denver Laboratory flotation cell. Examples 3 through 6 indicate procedures valuable for determining the optimum conditions of parameters such as addition levels for flotation reagents (e.g., collectors, activators, extenders, or depressants), order of addition, and effects of additives on each other. The pret'erred conditions for the particular flotation system and phosphate ore discussed herein are elaborated in Example 7. The addition level for the graft polymers is from 0.025 to about 0.2 pound/ton. However, the preferred addition level is from 0.025 to 0.05 pound/ton. The preferred polymer content is from about 2.5 to percent by weight of poly(l) in st-g-poly(l) and from about 2 to 11 percent by weight poly(l) and 5 to percent by weight poly(lll) in st-g-poly(l-co-lll).
EXAMPLE 1 Powdered wheat starch (100 g.; 9.8 percent moisture; 0.56 equivalent) was irradiated under a nitrogen atmosphere in a cobalt 60 source for 330 minutes at a dose rate of0.91 megarad/hour (total dosage 5.0 megarad) transferred to a reaction flask containing a nitrogen-prepurged aqueous solution of monomer (for reactions ofl, 475 ml. H O used; reaction with land 111, 550 ml. H O used). The reaction was allowed to proceed for 2 hours at 30 C. under a nitrogen atmosphere. The product was isolated by filtration after dilution of the reaction mixture with two volumes of isopropanol, washed successively with isopropanol and acetone, and dried 16 hours in vacuo at C. The products were analyzed for nitrogen, chlorine, and moisture. These values were used to calculate graft content and graft composition, Table I.
' Nitrogen and chlorine values too low for accurate estimation.
This monomer, 2-hydr0xy-3-methacryloyloxypropyltrimethylammonium chloride, is to be known herein as l. The acrylamide comonomer is to be known as 111. The starch graft polymers will be designated as st-gpoly(l) and st-g-poly(l-eo-lll) according to the method described by Battaerd and Tregear, (irufr Poly mum. lnterscienee Publishers, New York, New York, pages l4-l6.
To estimate the effectiveness of the starch graft polymers as silica depressants, a series of flotation runs were made with sand and a fatty acid amine collector (a good flotation aid for sand), Example 2, infra. The results show that flotation of the sand is significantly depressed by the addition, at 0.25 pound/ton (of sand),
EX AM PLE 2 Flotation studies with phosphate ore were conducted in a Denver Laboratory flotation cell using 1.0-kg. samples (dry weight) of deslimed. flotation grade (l655 mesh) ore (35.7 percent BPL and 56.5 percent acid insolubles) preconditioned at 70 percent solids with flotation reagents in a drill-press conditioning cell. Flotation reagents-4.14 pounds/ton of ore of tall oil fatty acid (collector) and No. 5 fuel oil (activator)--were added as a 1:1 mixture after addition of caustic to pH of 9. Depressants were added 0.10 percent dispersions with and before addition of flotation reagents. Overflow and tailing fractions were recovered by filtration, dried. and weighed. Portions of each were analyzed for phosphorous pentoxide and hydrochloric acid insolubles and results reported as BPL and acid insolubles content. Table 3.
EXAMPLE 4 Flotation studies were run as described in Example 3. except no graft polymer was added and the collector (tall oil fatty acids) was added as a 1:1 mixture with No. 5 fuel oil at various addition levels. For analyses. see Table 4.
EXAMPLE 5 Flotation studies were run as described in Example 3. except that the graft polymer from Run No. 5, Table 1, was added prior to the collector in various levels. The collector and activator were added at a 1.14-pound/ton level in each run. For analyses. see Table 5.
Table 3 Run Flotation Flotation Yield, Analyses, BPL No. conditions product BPL lnsols recovery 1 Blank Float 51.2 71.5 11.8 92.2 Tails 48.8 6.3 90.5 2 Graft polymer added with Float 50.0 72.2 10.5 89.9
flotation reagents Tails 50.0 8.1 88.2
3 Craft polymer added Float 41.4 75.7 7.2 78.1
before flotation reagents Tails 58.6 15.1 80.5
Graft polymer from Run N0. 5, Table 1.
Table 4 Additive level, Run lb./ton Flotation Yield, Analyses, BPL No. Collector product BPL lnsols recovery 4 0.91 Float 52.9 69.6 12.6 93.6 Tails 47.1 5.3 91.5 S 1.14 Float 54.1 68.8 14.3 94.1 Tails 45.9 5.1 91.7 6 1.37 Float 58.1 64.6 18.4 95.6 Tails 41.9 4.0 93.0 7 1.82 Float 60.6 63.6 20.5 97.0
Tails 39.4 3.0 94.8 Table 5 Additive level, Run lb./ton Flotation Yield, Analyses, BPL No SGP product BPL lnsols recovery 8 0.025 Float 36.0 73.6 9.5 67.7 Tails 64.0 19.7 63.0 9 0.050 Float 38.5 74.4 8.8 73.0 Tails 61.5 17.2 66.4 10 0.100 Float 43.4 72.8 10.1 79.4 Tails 56.6 14.5 60.0 l I 0.200 Float 53.0 70.4 12.9 94.3 Tails 47.0 4.8 90.2 5 Float 54.1 68.8 14.3 94.1
Tails 45.9 5.1 91.7
EXAMPLE 6 Flotation studies were run as described in Example 3, except 0.05 pound/ton of graft polymer (Run No. 5, Table l) was added prior to the addition of various amounts of collector (tall oil fatty acids; l:l mixture with No. fuel oil). For analyses. see Table 6.
EXAMPLE 7 Flotation studies were run as described in Example 3. Three different starch graft polymers were compared as silica depressants to two cationic starches and a wheat starch. Each was added prior to the addition of flotation reagents 1:1 mixture oftall oil fatty acids and oil fatty acids and No. 5 fuel oil and from 0.025 to 0.2 pound/ton of ore of a graft polymer comprised of a starch substrate onto which is grafted a member selected from the group consisting of a polymerized quaternary ammonium derivative of aminotrialkyl methacrylate and mixtures of a polymerized quaternary ammonium derivative of aminotrialkyl methacrylate with polyacrylamide; and b. collecting, filtering, and drying the resulting float. 2. The method described in claim 1 in which the graft polymer contains from about 2.5 to percent by weight of a polymerized quaternary ammonium derivative of aminotrialkyl methacrylate consisting of 2- No. 5 fuel oil each at the 1.14-pound/ton level), Table 15 hydroxy 3-methacwlwloxwmwltrimethylammonium chloride.
Table 6 Additive level, Run lb./ton Flotation Yield, Analyses, BPL No. Collector product BPL lnsols recovery 5 1.14 Float 54.1 68.8 14.3 94.1 Tails 45.9 5.1 91.7 12 0.91 Float 38.9 74.6 8.0 74.3 Tails 61.1 16.4 67.2 13 1.14 Float 38.5 74.4 8.8 73.0 Tails 61.5 17.2 66.4 14 1.37 Float 41.1 72.2 10.9 75.6 Tails 58.9 16.3 67.4 15 1.82 Float 44.2 69.7 13.1 77.9
Tails 55.8 15.7 68.5 Table 7 Additive Run Amount, Flotation Yield, M BPL No. Description lb./ton product BPL lnsols recovery 16 2 Float 45.5 72.6 10.0 84.6 Tails 54.5 1 1.0 84.2 l7 3 0.05 Float 17.6 75.9 7.0 73.2 Tails 52.4 16.7 77.0 9 5 0.05 Float 38.5 74.4 8.8 73.0 Tails 61.5 17.0 66.4 18 Wheat starch 0.10 Float 54.1 65.0 15.9 96.8 Tails 45.9 2.7 95.3 l9 Cationic starch 0.10 Float 53.3 66.0 18.1 90.5 Tails 46.7 8.0 87.3 20 Cationic starch 0.25 Float 50.0 67.0 11.4 91.5
Tails 50.0 6.2 90.1
Run no. from Table I.
We claim: 1. In a method of flotation-beneficiation of phosphate ores which normally includes the steps of:
a. floating the ore in the presence of tall oil fatty acids and No. 5 fuel oil; h. collecting the first float; I c. removing the tall oil fatty acids and No. 5 fuel oil from the first float; d. floating the first float in the presence of an amine collector; and e. collecting the second float; an improvement by which flotation is accomplished in a single stage, comprising the steps of:
a. froth floating phosphate ore in the presence of tall 3. The method described in claim I in which the graft polymer contains from about 2 to l 1 percent by weight of a polymerized quaternary ammonium derivative of aminotrialkyl methacrylate consisting of 2-hydroxy-3- methacryloyloxypropyltrimethylammonium chloride and from about 5 to 20 percent by weight polyacrylamide.
4. The method described in claim 2 in which the ore is floated in the presence of 0.05 pound/ton of ore of the starch graft polymer.
5. The method described in claim 3 in which the ore is floated in the presence of 0.05 pound/ton of ore of the starch graft polymer.
Claims (4)
- 2. The method described in claim 1 in which the graft polymer contains from about 2.5 to 15 percent by weight of a polymerized quaternary ammonium derivative of aminotrialkyl methacrylate consisting of 2-hydroxy-3-methacryloyloxypropyltrimethylammonium chloride.
- 3. The method described in claim 1 in which the graft polymer contains from about 2 to 11 percent by weight of a polymerized quaternary ammonium derivative of aminotrialkyl methacrylate consisting of 2-hydroxy-3-methacryloyloxypropyltrimethylammonium chloride and from about 5 to 20 percent by weight polyacrylamide.
- 4. The method described in claim 2 in which the ore is floated in the presence of 0.05 pound/ton of ore of the starch graft polymer.
- 5. The method described in claim 3 in which the ore is floated in the presence of 0.05 pound/ton of ore of the starch graft polymer.
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4309282A (en) * | 1980-04-14 | 1982-01-05 | American Cyanamid Company | Process of phosphate ore beneficiation in the presence of residual organic polymeric flocculants |
US4323487A (en) * | 1979-10-22 | 1982-04-06 | Henkel Corporation | Absorbent starch graft polymer and method of its preparation |
US4339331A (en) * | 1980-12-05 | 1982-07-13 | American Cyanamid Company | Crosslinked starches as depressants in mineral ore flotation |
US4377472A (en) * | 1976-08-03 | 1983-03-22 | W. R. Grace & Co. | Phosphate flotation |
US4853114A (en) * | 1988-04-05 | 1989-08-01 | American Cyanamid Copany | Method for the depressing of hydrous, layered silicates |
US20050284818A1 (en) * | 2004-06-28 | 2005-12-29 | Patterson Stanley A | Column flotation cell for enhanced recovery of minerals such as phosphates by froth flotation |
US11612898B2 (en) * | 2016-08-31 | 2023-03-28 | Kemira Oyj | Cationic polymer selective depressants and use thereof in mineral ore purification methods |
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US3575868A (en) * | 1965-03-04 | 1971-04-20 | Atlas Chem Ind | Flocculating agent comprising starch and polyacrylic acid |
US3635857A (en) * | 1969-12-12 | 1972-01-18 | Atlas Chem Ind | Graft copolymers of starch |
US3669915A (en) * | 1970-09-08 | 1972-06-13 | Us Agriculture | Flocculants from starch graft copolymers |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4377472A (en) * | 1976-08-03 | 1983-03-22 | W. R. Grace & Co. | Phosphate flotation |
US4323487A (en) * | 1979-10-22 | 1982-04-06 | Henkel Corporation | Absorbent starch graft polymer and method of its preparation |
US4309282A (en) * | 1980-04-14 | 1982-01-05 | American Cyanamid Company | Process of phosphate ore beneficiation in the presence of residual organic polymeric flocculants |
US4339331A (en) * | 1980-12-05 | 1982-07-13 | American Cyanamid Company | Crosslinked starches as depressants in mineral ore flotation |
US4853114A (en) * | 1988-04-05 | 1989-08-01 | American Cyanamid Copany | Method for the depressing of hydrous, layered silicates |
AU608430B2 (en) * | 1988-04-05 | 1991-03-28 | American Cyanamid Company | Method for the depressing of hydrated silicates |
US20050284818A1 (en) * | 2004-06-28 | 2005-12-29 | Patterson Stanley A | Column flotation cell for enhanced recovery of minerals such as phosphates by froth flotation |
US7510083B2 (en) | 2004-06-28 | 2009-03-31 | The Mosaic Company | Column flotation cell for enhanced recovery of minerals such as phosphates by froth flotation |
US20090145821A1 (en) * | 2004-06-28 | 2009-06-11 | Patterson Stanley A | Column flotation cell for enhanced recovery of minerals such as phosphates by froth flotation |
US8231008B2 (en) | 2004-06-28 | 2012-07-31 | Mos Holdings Inc. | Column flotation cell for enhanced recovery of minerals such as phosphates by froth flotation |
US11612898B2 (en) * | 2016-08-31 | 2023-03-28 | Kemira Oyj | Cationic polymer selective depressants and use thereof in mineral ore purification methods |
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