US3952180A - Cladding - Google Patents

Cladding Download PDF

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US3952180A
US3952180A US05/529,379 US52937974A US3952180A US 3952180 A US3952180 A US 3952180A US 52937974 A US52937974 A US 52937974A US 3952180 A US3952180 A US 3952180A
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cladding
accordance
substrate
clad
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Daniel S. Gnanamuthu
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Avco Everett Research Laboratory Inc
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/34Laser welding for purposes other than joining
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/20Bonding
    • B23K26/32Bonding taking account of the properties of the material involved
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/50Inorganic material, e.g. metals, not provided for in B23K2103/02 – B23K2103/26

Definitions

  • the present invention relates to cladding metals upon metallic substrates.
  • Surfaces may also be enhanced by cladding on materials through melting at the substrate surface, such as by laying rods of hard material on the metallic surface and melting by passing the flame of an oxy-acetylene torch thereover. Surfaces may also be enhanced by forming alloys in situ through deposition of minor alloy components and heating with a laser to produce melting and diffusion as taught in the co-pending application of Gnanamuthu, et al., Ser. No. 431,240, filed Jan. 7, 1974.
  • one or more units of cladding material are placed face to face with a substrate surface to be clad and a continuous wave output (cw) laser beam, is scanned along the cladding material to melt it.
  • the units are of elongated form, i.e., rod, wire or ribbon and the scanning is carried out longitudinally, i.e., parallel to the direction of elongation.
  • the rate of scanning is such that the melted material resolidifies very quickly as a bonded on clad at the substrate surface.
  • the molten material flows laterally along the substrate surface.
  • a laser beam core portion containing a majority of the radiant energy of the beam impacts the cladding material for melting and a fringe portion of the beam impacts the adjacent substrate surface area to make it more readily wettable by the molten cladding material and allow more uniform flow.
  • the relative motion between the substrate and laser beam for scanning may be effected by beam deflection, substrate movement or a combination of the two.
  • Multiple spaced units of cladding material may be placed on the substrate surface at the same time or in a sequence, synchronized with a scanning rate.
  • the resultant clad on layer often has a wavy form with peaks at the sites of cladding material placement. If it is desired to avoid the wavy surface of resultant clad material, then the clad on layer can be smoothed by locally oscillating the radiant energy beam during cladding and/or through multiple heating passes.
  • the spacing between units of cladding material is preferably at least one-half of unit width.
  • the radiant energy beam size for purposes of the present invention is from 0.025 inch to 1.0 inch diameter circle, or non-circular forms of the equivalent area, applied with a power of 1 to 20 kilowatts at a scanning rate of 5 to 50 inches per minute.
  • the cladding materials which may be advantageously applied through use of the present invention are cobalt, iron and/or nickel base alloys and other alloys or pure metals or intermatallic compounds.
  • the suitable substrates include essentially all metallic elements, compounds and alloys. However, the substrate material must not melt (excepting optionally, for a thin surface layer thereof as described below) under conditions of melting and superheating the cladding material.
  • FIG. 1 is an isometric, partly sectioned sketch of a substrate metallic plate being clad in accordance with a preferred embodiment of the process of the invention and indicating the scanning radiant energy beam which does the cladding;
  • FIG. 1A is a temperature-time profile for cooling the plate in the above process
  • FIGS. 2 and 2A are cross-sectional views of FIG. 1 materials after single and multiple cladding passes;
  • FIGS. 3 and 4 are isometric partly sectioned sketches of substrates being clad in accordance with further preferred embodiments of the invention, and;
  • FIG. 5 is a graph showing hardness profile of the clad and underlying substrate after treatment in accordance with a preferred embodiment of the invention.
  • FIG. 6 is a similar profile of alloying elements
  • FIGS. 7-10 are photomicrographs of clads made, respectively, in accordance with the prior art and the processes of the above described three embodiments of the present invention.
  • FIG. 11 is a drawing of a photomicrograph of a clad made in accordance with the processes of the present invention.
  • FIG. 1 there is shown a substrate plate 10 in the course of cladding in accordance with a preferred embodiment of the present invention.
  • a substrate plate 10 in the course of cladding in accordance with a preferred embodiment of the present invention.
  • three rods of cladding material have been applied and one of them, 12, has already been melted, another, 14, is in the course of melting and a third, 16, has not yet been melted.
  • the heat affected zone of the substrate underlying the first melted rod 12 is indicated at 18.
  • the melting is carried out by laser beam 20 having a core portion 22 and a fringe portion 24 of the beam.
  • the scanning is carried back and forth lengthwise along the rods with the loci of beam impact in successive scanning passes overlapping so that there will be a continuous heat affected zone running along the surface 11 of the substrate.
  • surface 11 Before cladding, surface 11 may be coated with a 1/4 - 1/2 mil thick layer of manganese phosphate using any of several known commercial phosphating processes or coated by application of a slurry of graphite in isopropyl alcohol and heating to drive off the alcohol to improve the radiant energy absorbtivity of the surface. Carbon black may also be applied as the absorbing coating.
  • the rods are not coated.
  • the cladding material may be in forms other than rod forms as indicated in the drawings, such as strips or spheres for instance. However, there should be spaces of exposed substrate surface between units of cladding material to allow the flow of molten cladding material.
  • FIG. 1A shows a typical profile for temperature vs. time in cooling, indicating a very rapid cooling from superheat temperature to melting point [A to B] to produce fine grain structure in the clad on part. Slow cooling down to C (about 800° F) prevents cracking and rapid cooling may be thereafter maintained down to room temperature.
  • an inert, reducing or carburizing atmosphere may be employed.
  • Use of a carburizing atmosphere is preferred on iron or steel parts to lower the melting point of a limited surface portion of the substrate to enhance flow of the molten cladding material thereon.
  • stellite rods are melted at approximately 2400° F and superheated to approximately 3000° F, cooled in half a second back to 2400° at 1200° F/sec. (A to B), then cooled for 15 minutes at 107° F/min.
  • the substrate e.g., steel
  • a surface layer thereof may be carburized in a suitable carburizing atmosphere, e.g., using an oxy-acetylene torch so that its melting point will be about 2600° F and this temperature is reached during cladding.
  • the core of the beam is preferably limited to a size smaller than the diameter or width of the cladding rod to avoid direct impingement on the substrate space between rods.
  • the rods absorb sufficient laser power that melting heat input to the substrate is avoided excepting in said limited surface portion thereof.
  • thick units of cladding material of at least 10 mils and preferably on the order of 50-200 mils are continuously arrayed in the path of the high power density beam.
  • FIG. 2 shows the resultant clad product produced in accordance with processing of FIG. 1 wherein the three melted rods 12, 14, and 16 are resolidifed as a continuous clad of wavy profile.
  • This waviness may be avoided by locally oscillating the laser beam in the course of melting; that is, by laterally or longitudinally oscillating the beam at a rate much higher than its scanning rate. Multiple passes, preferably with local oscillation, also tend to produce the greatest smoothness of the clad. Such smoothing techniques may be utilized to avoid the need for expensive surface grinding of the clad after completion of the process.
  • the resultant smoothed clad product is indicated in FIG. 2A wherein the clad-on-layer is indicated at 17.
  • a 1-20 kilowatt laser beam focused to a 0.025 to 0.7 inches diameter circle or area equivalent of other form with a core diameter of 1/8 - 1/2 total beam diameter is scanned across the surface to be clad at a rate of 5 to 25 inches per minute.
  • Power density of the core of the beam for cladding at the focal point can be considered to possess a 20 to 500 kw/in 2 .
  • the beam energy distribution is Gaussian and defines concentric Airy discs with the core disc being typically 1/8(0.025) inches and having a power density of 34.2 kw/cm 2 , the density averaged over the second Airy disc (1/4 inch diameter) being 13.4 kw/cm 2 for 10 kw of total laser power.
  • the rate of oscillating is such, in relation to scan rate, that the beam core impinges the same point at least 500, preferably at least 1000, times during the said period of molten state residence.
  • the beam will impinge the same point 1150 times.
  • the total energy applied is typically 1000-5000 Joules over a period of 100 or more milliseconds thereby allowing time for melting, superheating and smoothening flow of the cladding material.
  • the scan pattern is in linear traces of adjacent closely spaced parallel lines which work incrementally across an area to be clad.
  • Local oscillation if used, may be longitudinal (i.e., parallel to scan line direction), lateral (orthogonal to scan) or a combination of the two and/or may comprise beam cross-section-form changing such as a change from circular to cruciform or stellate.
  • the power density used for smoothening the successive clad zones is 20 to 50 percent of that for cladding. Typical times of residence in the molten state for any given portion of cladding material are 0.1 to 2.0 seconds. It is also possible to produce a laser beam without a high power density core relative to a low power density fringe, i.e., having substantially uniform power density, and such a beam may be essentially as wide as the diameter of the rods to be melted thereby. Heat transfer to the substrate via the cladding material provides the necessary substrate surface conditioning improving its wettability but limiting substrate melting to a superficial surface layer thereof, i.e., less than 1/5 of clad thickness.
  • High power lasers suitable for use in connection with the present invention may be the type shown in the copending application of Edward V. Locke and Richard A. Hella, Ser. No. 322,783, filed Jan. 11, 1973, now U.S. Pat. No. 3,817,606 of common assignment with the present application and in U.S. Pat. No. 3,702,973 granted Nov. 14, 1972, the disclosures of which are incorporated herein by reference as though set out at length herein.
  • Such lasers comprise an exciting electron beam source chamber and a gas lasing chamber with a lasing gas (e.g., a mixture of helium, nitrogen and carbon dioxide) and an optical cavity.
  • the electron beam initiates and sustains lasing activity within the optical cavity and an output light beam is controlled by deflection optics and beam tunnels to scan, and cut off (if necessary) the light beam.
  • FIGS. 3 and 4 show further preferred embodiments of the invention in which spaced units of cladding material are melted and resolidified to form a continuous clad-on layer on the surface of a substrate. Both embodiments are illustrated with respect to a substrate plate 32 mounted on a work table 34 which traverses in working passes, in a direction indicated by arrow 36, under a laser 38 which emits a beam 40.
  • the table makes incremental lateral steps by movement in the direction indicated by arrow 42 at the end of each working pass and retraces by movement in the direction indicated by arrow 44.
  • the laser beam may be shut off (deflected) during retrace or applied during retrace as desired.
  • the spaced units of cladding material comprise a layer of spaced powder particles 52 in FIG. 3 and, in FIG. 4, a wire 54 fed continuously by a feeder 56 to a point under the beam 40 in contact with the substrate surface.
  • the wire is fed in sequence along adjacent parallel paths, spaced from each other by a distance of one-half to one wire diameter.
  • the porosity of the loose powder provides the necessary spacing between units for flow of molten material and to limit the molten zone to a predetermined strip region related to laser beam width.
  • the wire feeding, together with the described workpiece displacement provides temporal as well as physical spacing between units of cladding material.
  • the laser and/or its beam may be moved in lieu of, or in addition to, workpiece displacement to effect scanning.
  • Multiple laser beams may be employed for the functions of melting and superheating the cladding material and heating adjacent substrate surface area to enhance the wettability of substrate surface to allow flow of molten cladding material thereon.
  • the spacing between units of cladding material on the substrate surface initially applied should be at least one-half the average span on the substrate surface of the units surrounding each space and no greater than a distance which would lead to discontinuity between adjacent melted and resolidified units.
  • spacings and cladding unit sizes will be in the same dimensional range, e.g., parallel 1/8-1/4 inch rods of cladding material spaced 1/8-1/4 inch apart (on a rod center-to-rod center basis).
  • circular cross-section rods may be placed side-by-side allowing the exposed substrate surface under their lower curves to constitute the flow distance.
  • a substrate plate of AISI 4815 steel was coated with a 1/4 mil thick layer of manganese phosphate and then preheated to about 450° to 500° F in a furnace. Then the plate was removed from the furnace and stellite rods of 1/8 inch diameter (Stellite Alloy No. 1, cast) were placed on the plate with a spacing of 1/4 inch between rods.
  • An unoscillated laser beam of approximately 1/8 inch in core diameter and 3 kilowatts power was scanned along the length of the rods, back and forth at a scanning rate of 10 inches per minute.
  • a mixture of argon flowing at 5 cubic feet per hour and hydrogen flowing at 10 cubic feet per hour were used as a shielding gas.
  • the stellite rods melted and flowed over the steel plate and resolidified as a well bonded clad.
  • the laser core power density was 66 kw/in 2 .
  • FIG. 5 shows hardness of the clad zone as a function of case depth of the clad-on layer.
  • the clad zone is 0.05 inch thick and in this zone hardness is between 58 and 63 on a Rockwell C scale while the hardness of the heat affected zone underlying the clad and of the base metal of the substrate is less than 30 on the same Rockwell C scale.
  • FIGS. 7 and 8 are microstructures of clads made in accordance with oxy-acetylene cladding and laser cladding, respectively.
  • the oxy-acetylene clad shows massive carbide particles of high hardness (Rockwell C70 or more) embedded in a soft matrix (Rockwell C45) and displays an overall hardness of Rockwell C51.
  • the laser clad shows a homongeneous and a fine microstructure of uniform hardness of Rockwell C60.
  • the same substrate and cladding materials as in Example I were processed through a second pass (after preheating at 900° F) using local oscillation of the laser beam which was scanned at a rate of 10 inches per minute with 5.25 kw power. Local oscillation was performed at 690 Hertz in a direction perpendicular to scanning.
  • the basic laser beam size was a rectangle of 1/8 inch long by 1/2 inch wide (the length dimension being parallel to the scanning direction and the width dimension being orthogonal thereto) and the scanning achieved an effective laser beam width of 1/2 in.
  • the laser processing was carried out in an atmosphere formed by argon flowing through at 5 cubic feet per hour and hydrogen at 10 cubic feet per hour.
  • the clad substrate was postheated at 900° F for 5 minutes.
  • the average hardness of the clad layer was 55 and that of the substrate was 20 (both on Rockwell C scale.)
  • the laser core power density was 23 kw/in 2 .
  • Cast Stellite Alloy No. 1 rods of 3/16 inch diameter spaced 3/16 inch apart were clad on AISI 4340 plate substrates, preheated to 900° F, by using a laser beam with a scanning speed of 10 inches/minute in an oxygen, acetylene gas mixture atmosphere under carburizing conditions.
  • the laser beam power was 12.75 kw.
  • the core power density was 280 kw/in 2 .
  • the clad substrate was post heated with oxy-acetylene flame for 3 minutes.
  • the clad-on layer had an average hardness of 60 (Rockwell C).
  • the base metal hardness was 36 (Rockwell C).
  • Rods of 3/16 inch diameter cast Stellite Alloy No. 6 were clad on AISI 4815 plate substrates preheated to 700° F, in oxygen, acetylene gas mixture under carburizing conditions.
  • the laser scanning speed was 10 inches per minute and laser power was 9 kw.
  • the core power density was 198 kw/in 2 .
  • the clad substrate was post heated with oxy-acetylene flame for 1 minute.
  • the resultant clad on layer had an average hardness of 48 (Rockwell C) and the average base metal hardness was 20 (Rockwell C).
  • Dura-Face alloys an alloy containing nickel, chromium, and silicates, manufactured by Inersoll Products Division of Borg Warner Corporation, was clad onto AISI C1080 plate substrates. No preheating or post heating was used. The working atmosphere comprised of argon flowing at 5 cubic feet per hour and hydrogen flowing at 5 cubic feet per hour. The scanning speed was 10 inches/minute. The thickness of applied cladding material was 0.080 inch. The width of applied cladding material was 1 inch. The laser power was 10.5 kw. The beam size was 1/2 inch wide by 1/8 inch long as that used in Example II. The core power density was 47 kw/in 2 . The average hardness of the clad-on layer was 64 (Rockwell C) and the average base metal hardness was 20 (Rockwell C).
  • AISI 304 stainless steel was clad on AISI C1018 plate substrates.
  • the scanning speed was 8 inches per minute. No preheating or post heating was used.
  • the laser power was 13.5 kw.
  • the effective beam size was 3/8 inch wide by 1/8 inch long.
  • the core power density was 80 kw/in 2 .
  • Hydrogen flowing at 10 cubic feet per hour formed the working atmosphere.
  • the thickness of cladding material was 0.040 inch and the width of the cladding material was 3/8 inches.
  • the average hardness of the clad-on layer was 88 (Rockwell B) and the base metal hardness was 88 (Rockwell B).
  • a cross-sectional view of the cladding is indicated in FIG. 9.
  • Nickel powder was spread on AISIC 1018 substrate plates and clad thereon by scanning at 20 in/min.
  • the nickel powder was -325 mesh size (U.S. standard corresponding to zero to 44 micron diameter spheres) and sprinkled on a substrate surface precoated with 1/4 mil thick manganese phosphates. Thickness of the powder sprinkled was 0.005 inch.
  • the working atmosphere was hydrogen flowing at 5 cubic feet per hour. No preheating or post heating was used.
  • Laser power was 9 kw and effective beam size was 1/8 inch long by 1/2 inch wide.
  • the core power density was 40 kw/in 2 .
  • a cross-section photomicrograph of the resultant product is shown in FIG. 10.
  • FIG. 11 is a drawing of a photomicrograph at five times magnification of a sawed and polished cross-section of a layer 12 clad to an AISI 4815 steel substrate in accordance with Examples I and corresponding essentially to the schematic illustration of a similar product in FIG. 2.
  • the heat affected zone 18 is bounded by an internal band 19 which is clearly recognizable at this level of magnification.

Abstract

A metal layer is clad to a metal substrate by laying spaced rods or wires of a cladding metal on the substrate surface and scanning the cladding metal with a continuously operating laser beam, part of which impinges directly on the cladding metal to melt it and part of which impinges on the adjacent surface area of the substrate to improve flow of molten metal thereon. The cladding metal may be fed to the substrate surface in synchronism with laser beam scanning. The process produces a clad layer of the cladding metal on the substrate characterized by a fine and homogeneous structure within the clad on layer and further characterized by uniform and high hardness compared to prior art cladding methods. The surface of the clad may be smoothed by locally oscillating the laser beam during the course of cladding and/or by multiple passes.

Description

BACKGROUND OF THE INVENTION
The present invention relates to cladding metals upon metallic substrates.
There are many known and long practiced methods for improving the resistance of fabricated or semifabricated metal (including elements, alloys and compounds) to wear, galling, spalling, deformation, corrosion, heating and/or erosion. These include overcoating the surface of the metal and modification of the composition and/or microstructure of the surface through such techniques as carburizing, nitriding, siliconizing, diffusion hardening, hard surfacing (welding a high-alloy layer to the surface), flame hardening, induction hardening and physical modification (e.g. peening). The overcoating methods include electroplating chromium or nickel onto the surface and roll cladding (for sheet form or wire form mill products). Surfaces may also be enhanced by cladding on materials through melting at the substrate surface, such as by laying rods of hard material on the metallic surface and melting by passing the flame of an oxy-acetylene torch thereover. Surfaces may also be enhanced by forming alloys in situ through deposition of minor alloy components and heating with a laser to produce melting and diffusion as taught in the co-pending application of Gnanamuthu, et al., Ser. No. 431,240, filed Jan. 7, 1974.
It is an important object of the present invention to provide a cladding method effective to produce high adherence of a thick layer of metal to the surface of a substrate.
It is a further object of the invention to provide fine and homogeneous microstructure within the clad-on layer consistent with the preceding object.
It is a further object of the invention to provide high and uniform hardness within the clad-on layer consistent with one or more of the preceding objects.
It is a further object of the invention to minimize interdiffusion between cladding and substrate materials consistent with one or more of the preceding objects.
It is a further object of the invention to provide a smooth clad surface consistent with one or more of the preceding objects.
It is a further object of the invention to provide high density - low porosity surface layers of materials consistent with one or more of the preceding objects.
It is a further object of the invention to utilize standard equipments borrowed from other major purposes and not necessarily dedicated to surface modification consistent with one or more of the preceding objects.
It is a further object of the invention to provide flexibility of process control consistent with one or more of the preceding objects.
It is a further object of the invention to minimize incidental effects on the substrate below the surface layer consistent with one or more of the preceding objects.
It is a further object of the invention to provide minimal working time and related substrate preparation and posttreatment times consistent with one or more of the preceding objects.
SUMMARY OF THE INVENTION
In accordance with the invention, one or more units of cladding material are placed face to face with a substrate surface to be clad and a continuous wave output (cw) laser beam, is scanned along the cladding material to melt it. The units are of elongated form, i.e., rod, wire or ribbon and the scanning is carried out longitudinally, i.e., parallel to the direction of elongation. The rate of scanning is such that the melted material resolidifies very quickly as a bonded on clad at the substrate surface. During the brief time of residence in the molten state, the molten material flows laterally along the substrate surface.
A laser beam core portion containing a majority of the radiant energy of the beam impacts the cladding material for melting and a fringe portion of the beam impacts the adjacent substrate surface area to make it more readily wettable by the molten cladding material and allow more uniform flow. The relative motion between the substrate and laser beam for scanning may be effected by beam deflection, substrate movement or a combination of the two.
Multiple spaced units of cladding material may be placed on the substrate surface at the same time or in a sequence, synchronized with a scanning rate. The resultant clad on layer often has a wavy form with peaks at the sites of cladding material placement. If it is desired to avoid the wavy surface of resultant clad material, then the clad on layer can be smoothed by locally oscillating the radiant energy beam during cladding and/or through multiple heating passes. The spacing between units of cladding material is preferably at least one-half of unit width.
It has been found in the practice of the invention that massive reinforcing particles of high hardness in the cladding material such as carbide particles in stellite alloy rods are dissolved in the melting cladding material and upon resolidification are reproduced in the matrix at a much finer scale than they originally appeared in the rods, thereby giving the clad on layer a high uniform hardness. This is in contrast to microstructures observed in such conventional processes as oxy-acetylene cladding wherein large inclusions of carbide particles may be observed in the finished clad. Starting composition of the cladding material is preserved in the final product of the present invention; there is very low interdiffusion with or dilution by substrate material.
The radiant energy beam size for purposes of the present invention is from 0.025 inch to 1.0 inch diameter circle, or non-circular forms of the equivalent area, applied with a power of 1 to 20 kilowatts at a scanning rate of 5 to 50 inches per minute. Among the cladding materials which may be advantageously applied through use of the present invention are cobalt, iron and/or nickel base alloys and other alloys or pure metals or intermatallic compounds. The suitable substrates include essentially all metallic elements, compounds and alloys. However, the substrate material must not melt (excepting optionally, for a thin surface layer thereof as described below) under conditions of melting and superheating the cladding material.
These and other objects, features and advantages of the invention will be apparent from the following detailed description of preferred embodiments of the invention taken in conjunction with the accompanying drawing in which:
BRIEF DESCRIPTION OF THE DRAWING
FIG. 1 is an isometric, partly sectioned sketch of a substrate metallic plate being clad in accordance with a preferred embodiment of the process of the invention and indicating the scanning radiant energy beam which does the cladding;
FIG. 1A is a temperature-time profile for cooling the plate in the above process;
FIGS. 2 and 2A are cross-sectional views of FIG. 1 materials after single and multiple cladding passes;
FIGS. 3 and 4 are isometric partly sectioned sketches of substrates being clad in accordance with further preferred embodiments of the invention, and;
FIG. 5 is a graph showing hardness profile of the clad and underlying substrate after treatment in accordance with a preferred embodiment of the invention;
FIG. 6 is a similar profile of alloying elements;
FIGS. 7-10 are photomicrographs of clads made, respectively, in accordance with the prior art and the processes of the above described three embodiments of the present invention;
FIG. 11 is a drawing of a photomicrograph of a clad made in accordance with the processes of the present invention.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
Referring now to FIG. 1, there is shown a substrate plate 10 in the course of cladding in accordance with a preferred embodiment of the present invention. For purposes of this illustration, it is indicated that three rods of cladding material have been applied and one of them, 12, has already been melted, another, 14, is in the course of melting and a third, 16, has not yet been melted. The heat affected zone of the substrate underlying the first melted rod 12 is indicated at 18. The melting is carried out by laser beam 20 having a core portion 22 and a fringe portion 24 of the beam. The scanning is carried back and forth lengthwise along the rods with the loci of beam impact in successive scanning passes overlapping so that there will be a continuous heat affected zone running along the surface 11 of the substrate.
Before cladding, surface 11 may be coated with a 1/4 - 1/2 mil thick layer of manganese phosphate using any of several known commercial phosphating processes or coated by application of a slurry of graphite in isopropyl alcohol and heating to drive off the alcohol to improve the radiant energy absorbtivity of the surface. Carbon black may also be applied as the absorbing coating. The rods are not coated. Also, before cladding, it is preferable to preheat the substrate 10, typically to about 400° -700° C, and then apply the cladding material. The cladding material may be in forms other than rod forms as indicated in the drawings, such as strips or spheres for instance. However, there should be spaces of exposed substrate surface between units of cladding material to allow the flow of molten cladding material.
The clad parts are preferably post heated to avoid formation of cracks caused by rapid cooling. FIG. 1A shows a typical profile for temperature vs. time in cooling, indicating a very rapid cooling from superheat temperature to melting point [A to B] to produce fine grain structure in the clad on part. Slow cooling down to C (about 800° F) prevents cracking and rapid cooling may be thereafter maintained down to room temperature.
During laser scanning, an inert, reducing or carburizing atmosphere may be employed. Use of a carburizing atmosphere is preferred on iron or steel parts to lower the melting point of a limited surface portion of the substrate to enhance flow of the molten cladding material thereon.
For a typical case, stellite rods are melted at approximately 2400° F and superheated to approximately 3000° F, cooled in half a second back to 2400° at 1200° F/sec. (A to B), then cooled for 15 minutes at 107° F/min. The substrate (e.g., steel) stays below its melting point of 2700° -2800° F. But a surface layer thereof may be carburized in a suitable carburizing atmosphere, e.g., using an oxy-acetylene torch so that its melting point will be about 2600° F and this temperature is reached during cladding.
The core of the beam is preferably limited to a size smaller than the diameter or width of the cladding rod to avoid direct impingement on the substrate space between rods. The rods absorb sufficient laser power that melting heat input to the substrate is avoided excepting in said limited surface portion thereof. To this end thick units of cladding material of at least 10 mils and preferably on the order of 50-200 mils are continuously arrayed in the path of the high power density beam.
FIG. 2 shows the resultant clad product produced in accordance with processing of FIG. 1 wherein the three melted rods 12, 14, and 16 are resolidifed as a continuous clad of wavy profile. This waviness may be avoided by locally oscillating the laser beam in the course of melting; that is, by laterally or longitudinally oscillating the beam at a rate much higher than its scanning rate. Multiple passes, preferably with local oscillation, also tend to produce the greatest smoothness of the clad. Such smoothing techniques may be utilized to avoid the need for expensive surface grinding of the clad after completion of the process. The resultant smoothed clad product is indicated in FIG. 2A wherein the clad-on-layer is indicated at 17.
Preferably, a 1-20 kilowatt laser beam focused to a 0.025 to 0.7 inches diameter circle or area equivalent of other form with a core diameter of 1/8 - 1/2 total beam diameter, is scanned across the surface to be clad at a rate of 5 to 25 inches per minute. Power density of the core of the beam for cladding at the focal point can be considered to possess a 20 to 500 kw/in2. The beam energy distribution is Gaussian and defines concentric Airy discs with the core disc being typically 1/8(0.025) inches and having a power density of 34.2 kw/cm2, the density averaged over the second Airy disc (1/4 inch diameter) being 13.4 kw/cm2 for 10 kw of total laser power.
In local oscillation, the rate of oscillating is such, in relation to scan rate, that the beam core impinges the same point at least 500, preferably at least 1000, times during the said period of molten state residence. For instance, during a 9 inch per minute scan by a 1/4 inch beam (calculated on second Airy disc) locally oscillated at 690 Hertz, over half an inch of lateral travel, the beam will impinge the same point 1150 times. The total energy applied is typically 1000-5000 Joules over a period of 100 or more milliseconds thereby allowing time for melting, superheating and smoothening flow of the cladding material.
The scan pattern is in linear traces of adjacent closely spaced parallel lines which work incrementally across an area to be clad. Local oscillation, if used, may be longitudinal (i.e., parallel to scan line direction), lateral (orthogonal to scan) or a combination of the two and/or may comprise beam cross-section-form changing such as a change from circular to cruciform or stellate.
The power density used for smoothening the successive clad zones is 20 to 50 percent of that for cladding. Typical times of residence in the molten state for any given portion of cladding material are 0.1 to 2.0 seconds. It is also possible to produce a laser beam without a high power density core relative to a low power density fringe, i.e., having substantially uniform power density, and such a beam may be essentially as wide as the diameter of the rods to be melted thereby. Heat transfer to the substrate via the cladding material provides the necessary substrate surface conditioning improving its wettability but limiting substrate melting to a superficial surface layer thereof, i.e., less than 1/5 of clad thickness.
It is important to control heating conditions so that the cladding material not only melts, but is superheated so that the lowest melting phase dissolves other phases thereof. In the case of stellite rods, this superheating allows massive carbide particle inclusions to be dissolved. The rapid rate of scanning allows quick cooling and prevents the regrowth of precipitates.
High power lasers suitable for use in connection with the present invention may be the type shown in the copending application of Edward V. Locke and Richard A. Hella, Ser. No. 322,783, filed Jan. 11, 1973, now U.S. Pat. No. 3,817,606 of common assignment with the present application and in U.S. Pat. No. 3,702,973 granted Nov. 14, 1972, the disclosures of which are incorporated herein by reference as though set out at length herein. Such lasers comprise an exciting electron beam source chamber and a gas lasing chamber with a lasing gas (e.g., a mixture of helium, nitrogen and carbon dioxide) and an optical cavity. The electron beam initiates and sustains lasing activity within the optical cavity and an output light beam is controlled by deflection optics and beam tunnels to scan, and cut off (if necessary) the light beam.
FIGS. 3 and 4 show further preferred embodiments of the invention in which spaced units of cladding material are melted and resolidified to form a continuous clad-on layer on the surface of a substrate. Both embodiments are illustrated with respect to a substrate plate 32 mounted on a work table 34 which traverses in working passes, in a direction indicated by arrow 36, under a laser 38 which emits a beam 40. The table makes incremental lateral steps by movement in the direction indicated by arrow 42 at the end of each working pass and retraces by movement in the direction indicated by arrow 44. The laser beam may be shut off (deflected) during retrace or applied during retrace as desired.
In both FIGS. 3 and 4, two rows 46 of clad have been formed and a third row 48 is partially completed. In the remaining unworked area 50 of the substrate surface the spaced units of cladding material comprise a layer of spaced powder particles 52 in FIG. 3 and, in FIG. 4, a wire 54 fed continuously by a feeder 56 to a point under the beam 40 in contact with the substrate surface. The wire is fed in sequence along adjacent parallel paths, spaced from each other by a distance of one-half to one wire diameter.
In the FIG. 3 embodiment, the porosity of the loose powder provides the necessary spacing between units for flow of molten material and to limit the molten zone to a predetermined strip region related to laser beam width.
In the FIG. 4 embodiment, the wire feeding, together with the described workpiece displacement provides temporal as well as physical spacing between units of cladding material.
In all the embodiments of the invention the laser and/or its beam may be moved in lieu of, or in addition to, workpiece displacement to effect scanning. Multiple laser beams may be employed for the functions of melting and superheating the cladding material and heating adjacent substrate surface area to enhance the wettability of substrate surface to allow flow of molten cladding material thereon. The spacing between units of cladding material on the substrate surface initially applied should be at least one-half the average span on the substrate surface of the units surrounding each space and no greater than a distance which would lead to discontinuity between adjacent melted and resolidified units. Preferably, spacings and cladding unit sizes will be in the same dimensional range, e.g., parallel 1/8-1/4 inch rods of cladding material spaced 1/8-1/4 inch apart (on a rod center-to-rod center basis). In the extreme case, circular cross-section rods may be placed side-by-side allowing the exposed substrate surface under their lower curves to constitute the flow distance.
The practice of the invention is further illustrated by the following non-limiting examples. All of the values given for laser beam power and power density given in the following examples are given for that calculated to be at the surface of the workpiece.
EXAMPLE 1
A substrate plate of AISI 4815 steel was coated with a 1/4 mil thick layer of manganese phosphate and then preheated to about 450° to 500° F in a furnace. Then the plate was removed from the furnace and stellite rods of 1/8 inch diameter (Stellite Alloy No. 1, cast) were placed on the plate with a spacing of 1/4 inch between rods. An unoscillated laser beam of approximately 1/8 inch in core diameter and 3 kilowatts power was scanned along the length of the rods, back and forth at a scanning rate of 10 inches per minute. A mixture of argon flowing at 5 cubic feet per hour and hydrogen flowing at 10 cubic feet per hour were used as a shielding gas. The stellite rods melted and flowed over the steel plate and resolidified as a well bonded clad. The laser core power density was 66 kw/in2.
FIG. 5 shows hardness of the clad zone as a function of case depth of the clad-on layer. The clad zone is 0.05 inch thick and in this zone hardness is between 58 and 63 on a Rockwell C scale while the hardness of the heat affected zone underlying the clad and of the base metal of the substrate is less than 30 on the same Rockwell C scale. FIG. 6 shows chemical composition of the clad zone as a function of depth of the clad wherein it is seen that the concentration of the stellite ingredients, cobalt, chromium, and tungsten, is essentially constant with depth and in amounts corresponding essentially to that of the original stellite rods, thus indicating that during laser cladding there is very little dilution of the cladding material with substrate material.
FIGS. 7 and 8 are microstructures of clads made in accordance with oxy-acetylene cladding and laser cladding, respectively. The oxy-acetylene clad shows massive carbide particles of high hardness (Rockwell C70 or more) embedded in a soft matrix (Rockwell C45) and displays an overall hardness of Rockwell C51. On the other hand, the laser clad shows a homongeneous and a fine microstructure of uniform hardness of Rockwell C60.
EXAMPLE 2
The same substrate and cladding materials as in Example I were processed through a second pass (after preheating at 900° F) using local oscillation of the laser beam which was scanned at a rate of 10 inches per minute with 5.25 kw power. Local oscillation was performed at 690 Hertz in a direction perpendicular to scanning. The basic laser beam size was a rectangle of 1/8 inch long by 1/2 inch wide (the length dimension being parallel to the scanning direction and the width dimension being orthogonal thereto) and the scanning achieved an effective laser beam width of 1/2 in. The laser processing was carried out in an atmosphere formed by argon flowing through at 5 cubic feet per hour and hydrogen at 10 cubic feet per hour. The clad substrate was postheated at 900° F for 5 minutes. The result was that the clad surface was made essentially flat in contrast to a wavy surface in the product of Example I. The average hardness of the clad layer was 55 and that of the substrate was 20 (both on Rockwell C scale.) The laser core power density was 23 kw/in2.
EXAMPLE III
Cast Stellite Alloy No. 1 rods of 3/16 inch diameter spaced 3/16 inch apart were clad on AISI 4340 plate substrates, preheated to 900° F, by using a laser beam with a scanning speed of 10 inches/minute in an oxygen, acetylene gas mixture atmosphere under carburizing conditions. The laser beam power was 12.75 kw. The core power density was 280 kw/in2. The clad substrate was post heated with oxy-acetylene flame for 3 minutes. The clad-on layer had an average hardness of 60 (Rockwell C). The base metal hardness was 36 (Rockwell C).
EXAMPLE IV
Rods of 3/16 inch diameter cast Stellite Alloy No. 6 were clad on AISI 4815 plate substrates preheated to 700° F, in oxygen, acetylene gas mixture under carburizing conditions. The laser scanning speed was 10 inches per minute and laser power was 9 kw. The core power density was 198 kw/in2. The clad substrate was post heated with oxy-acetylene flame for 1 minute. The resultant clad on layer had an average hardness of 48 (Rockwell C) and the average base metal hardness was 20 (Rockwell C).
EXAMPLE V
Dura-Face alloys an alloy containing nickel, chromium, and silicates, manufactured by Inersoll Products Division of Borg Warner Corporation, was clad onto AISI C1080 plate substrates. No preheating or post heating was used. The working atmosphere comprised of argon flowing at 5 cubic feet per hour and hydrogen flowing at 5 cubic feet per hour. The scanning speed was 10 inches/minute. The thickness of applied cladding material was 0.080 inch. The width of applied cladding material was 1 inch. The laser power was 10.5 kw. The beam size was 1/2 inch wide by 1/8 inch long as that used in Example II. The core power density was 47 kw/in2. The average hardness of the clad-on layer was 64 (Rockwell C) and the average base metal hardness was 20 (Rockwell C).
EXAMPLE VI
AISI 304 stainless steel was clad on AISI C1018 plate substrates. The scanning speed was 8 inches per minute. No preheating or post heating was used. The laser power was 13.5 kw. The effective beam size was 3/8 inch wide by 1/8 inch long. The core power density was 80 kw/in2. Hydrogen flowing at 10 cubic feet per hour formed the working atmosphere. The thickness of cladding material was 0.040 inch and the width of the cladding material was 3/8 inches. The average hardness of the clad-on layer was 88 (Rockwell B) and the base metal hardness was 88 (Rockwell B). A cross-sectional view of the cladding is indicated in FIG. 9.
EXAMPLE VII
Nickel powder was spread on AISIC 1018 substrate plates and clad thereon by scanning at 20 in/min. The nickel powder was -325 mesh size (U.S. standard corresponding to zero to 44 micron diameter spheres) and sprinkled on a substrate surface precoated with 1/4 mil thick manganese phosphates. Thickness of the powder sprinkled was 0.005 inch. The working atmosphere was hydrogen flowing at 5 cubic feet per hour. No preheating or post heating was used. Laser power was 9 kw and effective beam size was 1/8 inch long by 1/2 inch wide. The core power density was 40 kw/in2. A cross-section photomicrograph of the resultant product is shown in FIG. 10.
FIG. 11 is a drawing of a photomicrograph at five times magnification of a sawed and polished cross-section of a layer 12 clad to an AISI 4815 steel substrate in accordance with Examples I and corresponding essentially to the schematic illustration of a similar product in FIG. 2. The heat affected zone 18 is bounded by an internal band 19 which is clearly recognizable at this level of magnification.
It is evident that those skilled in the art, once given the benefit of the foregoing disclosure, may now make numerous other uses and modifications of, and departures from the specific embodiments described herein without departing from the inventive concepts. Consequently, the invention is to be construed as embracing each and every novel feature and novel combination of features present in, or possessed by the apparatus and techniques herein disclosed and limited solely by the scope and spirit of the appended claims.

Claims (17)

What is claimed:
1. Cladding method comprising,
continuously scanning a metal substrate surface with a CW operating laser beam having a core power density of 29 to 500 kilowatts per square inch in linear traces with a longitudinal scanning speed along such linear trace of 5-50 inches per minute.
the scanning being carried out in a pattern to incrementally trace the surface with spaced scan line patterns,
simultaneously feeding a cladding metal to the substrate surface to intercept essentially the entire laser beam core and absorb essentially the entire beam energy so that the cladding material is melted and superheated and with application of laser beam power thereto for an essentially continuous period of at least 100 milliseconds and so that the adjacent substrate surface is heat treated at the same time to improve its wettability but melted only to the extent of a superficial surface layer thereof.
2. Cladding method in accordance with claim 1 wherein the cladding material is fed in elongated form having a width dimension perpendicular to the scan line direction with a spacing of at least one-half said width dimension between the loci of material feed along adjacent spaced scan lines.
3. Cladding method in accordance with claim 1 and further comprising,
locally oscillating the laser beam while scanning.
4. Cladding method in accordance with claim 1 and further comprising,
rescanning the clad surface with a laser beam to smooth the clad.
5. Cladding method in accordance with claim 4 wherein the laser beam used for rescanning is maintained at 20 to 50 per cent of power density of the original beam used for cladding.
6. Cladding method comprising,
butting elongated spaced units of cladding material against the surface of a substrate of higher melting point than the cladding material,
the average spacing between units being at least one-half of average unit width,
impinging a beam of radiant energy from a CW laser upon the cladding material units to heat said units and adjacent surface areas of the substrate,
relatively scanning the beam longitudinally along said units of cladding material and controlling heat input to melt and superheat the units of cladding material while simultaneously heating the adjacent substrate surface areas to enhance the flow of molten cladding material thereon,
and wherein the laser beam is focused to a 0.025 to 1.0 inch diameter circle, or area equivalent of other form, scans along the cladding units at a rate 5 to 50 inches per minute and comprises a power of 1 to 20 kilowatts.
7. Cladding method in accordance with claim 6 wherein the cladding material units comprise rod or wire form.
8. Cladding method in accordance with claim 6 wherein the laser beam is locally oscillated while scanning.
9. Cladding method in accordance with claim 6 wherein the laser beam has a high power density core portion of less lateral width than said units and an outer low power density fringe which impinges directly on the space between units.
10. Cladding method in accordance with claim 6 wherein the laser beam is of essentially the same width as the width of said units and has a substantially uniform power density.
11. Cladding method in accordance with claim 6 wherein temperature of the cladding material is controlled after superheating to cool said material from superheat temperature to its melting (freezing) point at a first rapid rate to maintain fine grain structure therein,
and is thereafter cooled more slowly down to below about 1000° F at a second slower rate to avoid cracking.
12. Cladding method in accordance with claim 11 wherein said first rate is above 1000° F per minute and said second rate is below 1000° F per minute.
13. Cladding method in accordance with claim 6 and further comprising,
treating a surface layer of the substrate to lower its melting point while cladding so that a thin skin portion of said surface layer melts under cladding conditions.
14. Cladding method in accordance with claim 6 and further comprising,
rescanning said radiant energy beam across the clad parts in at least one additional scan after cladding to smooth the clad surface.
15. Cladding method in accordance with claim 14 wherein said additional scanning passes are made at lower power density than used for cladding.
16. Cladding method in accordance with claim 6 and further comprising,
providing temporal as well as physical spacing of the arrangement of said spaced units.
17. Cladding method in accordance with claim 16 wherein
a length of cladding material is continuously fed into a radiant energy beam through relative movement thereof while providing relative movement between a substrate and the meeting point of the beam and material,
said point being between the surface of said substrate and the source of radiant energy beam.
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Cited By (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4015100A (en) * 1974-01-07 1977-03-29 Avco Everett Research Laboratory, Inc. Surface modification
US4059876A (en) * 1976-11-03 1977-11-29 General Motors Corporation Method of alloying and forming a valve seat
US4125926A (en) * 1975-09-02 1978-11-21 Caterpillar Tractor Co. Method of making aluminum piston with reinforced piston ring groove
US4157923A (en) * 1976-09-13 1979-06-12 Ford Motor Company Surface alloying and heat treating processes
US4239556A (en) * 1978-12-22 1980-12-16 General Electric Company Sensitized stainless steel having integral normalized surface region
US4260095A (en) * 1978-08-18 1981-04-07 Smith Phillip H Method of manufacturing a clad product
US4322601A (en) * 1978-08-14 1982-03-30 Serlin Richard A Surface alloying method and apparatus using high energy beam
US4323756A (en) * 1979-10-29 1982-04-06 United Technologies Corporation Method for fabricating articles by sequential layer deposition
US4348263A (en) * 1980-09-12 1982-09-07 Western Electric Company, Inc. Surface melting of a substrate prior to plating
US4451299A (en) * 1982-09-22 1984-05-29 United Technologies Corporation High temperature coatings by surface melting
US4468552A (en) * 1982-09-29 1984-08-28 Advanced Technologies, Inc. Method of applying hard surfaces to gate valves and the like
US4495255A (en) * 1980-10-30 1985-01-22 At&T Technologies, Inc. Laser surface alloying
US4644127A (en) * 1984-08-20 1987-02-17 Fiat Auto S.P.A. Method of carrying out a treatment on metal pieces with the addition of an added material and with the use of a power laser
US4663513A (en) * 1985-11-26 1987-05-05 Spectra-Physics, Inc. Method and apparatus for monitoring laser processes
US4725708A (en) * 1985-07-17 1988-02-16 Toyota Jidosha Kabushiki Kaisha Method for padding a copper type alloy material upon a base of aluminum type metal using laser beam oscillating transversely to its tracking direction
US4743733A (en) * 1984-10-01 1988-05-10 General Electric Company Method and apparatus for repairing metal in an article
US4785775A (en) * 1984-12-20 1988-11-22 Sulzer Brothers Limited Wear layer for piston and cylinder of an internal combustion engine
US4803334A (en) * 1987-11-16 1989-02-07 Westinghouse Electric Corp. Method for laser beam welding metal matrix composite components
US4835357A (en) * 1988-06-20 1989-05-30 Williams International Corporation Sheet metal laser welding
US4873416A (en) * 1987-08-27 1989-10-10 Rheinmetall Gmbh Method for the application and fastening of rotating bands on projectile bodies
US4926022A (en) * 1989-06-20 1990-05-15 Digital Equipment Corporation Laser reflow soldering process and bonded assembly formed thereby
DE3928092A1 (en) * 1989-08-25 1991-02-28 Mordike Barry Leslie Coating metal surfaces using laser-wire coating method - with wire electro-resistance preheated to improve flow capabilities and improve coating qualities
US5084113A (en) * 1985-05-24 1992-01-28 Toyota Jidosha Kabushiki Kaisha Method of producing a buildup valve for use in internal combustion engines
US5127364A (en) * 1989-12-18 1992-07-07 General Electric Company Apparatus for making A-15 type tape superconductors which includes means to melt a wire at its tip so a beam is formed and means for wiping the bead onto a continuous tape substrate
EP0698800A1 (en) 1994-08-25 1996-02-28 Fraunhofer-Gesellschaft Zur Förderung Der Angewandten Forschung E.V. Process for controlling the laserbeam intensity repartition for processing element surfaces
US5578227A (en) * 1996-11-22 1996-11-26 Rabinovich; Joshua E. Rapid prototyping system
US5759641A (en) * 1996-05-15 1998-06-02 Dimitrienko; Ludmila Nikolaevna Method of applying strengthening coatings to metallic or metal-containing surfaces
US5889254A (en) * 1995-11-22 1999-03-30 General Electric Company Method and apparatus for Nd: YAG hardsurfacing
US6144008A (en) * 1996-11-22 2000-11-07 Rabinovich; Joshua E. Rapid manufacturing system for metal, metal matrix composite materials and ceramics
US6146476A (en) * 1999-02-08 2000-11-14 Alvord-Polk, Inc. Laser-clad composite cutting tool and method
US6441338B1 (en) 1999-04-19 2002-08-27 Joshua E. Rabinovich Rapid manufacturing of steel rule dies and other 3-dimensional products, apparatus, process and products
US20060163521A1 (en) * 2005-01-26 2006-07-27 Honeywell International, Inc. Solid-free-form fabrication of hot gas valve discs
US20090274923A1 (en) * 2008-03-04 2009-11-05 Kenneth Hall Tools Having Compacted Powder Metal Work Surfaces, And Method
US20100155374A1 (en) * 2008-11-04 2010-06-24 Rabinovich Joshua E process for energy beam solid-state metallurgical bonding of wires having two or more flat surfaces
US20100255630A1 (en) * 2008-01-18 2010-10-07 Miasole Sodium-incorporation in solar cell substrates and contacts
US20100258982A1 (en) * 2008-01-18 2010-10-14 Miasole Laser polishing of a solar cell substrate
US20110000953A1 (en) * 2008-03-07 2011-01-06 The Ohio State University Low-temperature spot impact welding driven without contact
US20110106290A1 (en) * 2009-10-30 2011-05-05 Hoevel Simone Method of applying multiple materials with selective laser melting on a 3d article
US8546172B2 (en) 2008-01-18 2013-10-01 Miasole Laser polishing of a back contact of a solar cell
WO2015065655A1 (en) 2013-11-04 2015-05-07 Caterpillar Inc. Laser cladding with a laser scanning head
US9168613B2 (en) 2010-10-22 2015-10-27 Paul T. Colby Vertical laser cladding system
US20150343563A1 (en) * 2013-02-01 2015-12-03 Siemens Aktiengesellschaft Welding method having welding power depending upon thickness
US20150377089A1 (en) * 2014-06-30 2015-12-31 Mahle International Gmbh Valve for internal combustion engines and method for obtaining a valve
US9228609B2 (en) 2013-08-16 2016-01-05 Caterpillar Inc. Laser cladding fabrication method
US9289845B2 (en) 2012-11-07 2016-03-22 David S. Henn Metal deposition of exterior members in oil field tubulars
US20170239751A1 (en) * 2014-11-12 2017-08-24 Jiangsu University Laser thermal combination remanufacturing method for damaged metal part
US10138528B2 (en) 2012-09-06 2018-11-27 Etxe-Tar, S.A. Method and system for laser hardening of a surface of a workpiece
US20190126387A1 (en) * 2016-04-08 2019-05-02 Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E.V. Device and method for producing metallic components
US10864603B2 (en) 2015-03-17 2020-12-15 Ikergune A.I.E. Method and system for heat treatment of sheet metal

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59135886U (en) 1983-02-28 1984-09-11 川崎製鉄株式会社 laser welding machine
US4684781A (en) 1985-01-29 1987-08-04 Physical Sciences, Inc. Method for bonding using laser induced heat and pressure
EP0496181B1 (en) 1991-01-21 1998-08-19 Sulzer Hydro AG Method of fabricating metallic workpieces with a welding apparatus, and apparatus for carrying out the method
US5160822A (en) * 1991-05-14 1992-11-03 General Electric Company Method for depositing material on the tip of a gas turbine engine airfoil using linear translational welding
US5514849A (en) * 1993-02-17 1996-05-07 Electric Power Research Institute, Inc. Rotating apparatus for repairing damaged tubes
US5430270A (en) * 1993-02-17 1995-07-04 Electric Power Research Institute, Inc. Method and apparatus for repairing damaged tubes
US5653897A (en) * 1993-02-17 1997-08-05 Electric Power Research Institute Rotating fiber optic coupler for high power laser welding applications
US5393482A (en) * 1993-10-20 1995-02-28 United Technologies Corporation Method for performing multiple beam laser sintering employing focussed and defocussed laser beams
US8505414B2 (en) * 2008-06-23 2013-08-13 Stanley Black & Decker, Inc. Method of manufacturing a blade
US8769833B2 (en) 2010-09-10 2014-07-08 Stanley Black & Decker, Inc. Utility knife blade
US8733422B2 (en) * 2012-03-26 2014-05-27 Apple Inc. Laser cladding surface treatments
US10856443B2 (en) 2018-06-06 2020-12-01 Apple Inc. Cladded metal structures for dissipation of heat in a portable electronic device
EP3791978A1 (en) 2019-09-13 2021-03-17 Rolls-Royce Corporation Additive manufactured ferrous components

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3139511A (en) * 1961-05-18 1964-06-30 Standard Pressed Steel Co Fusion cladding technique and product
US3185814A (en) * 1961-12-30 1965-05-25 Siemens Ag Method and apparatus for overlay welding
US3296408A (en) * 1966-02-01 1967-01-03 R I Patents Inc Dual arc welding
US3428774A (en) * 1964-06-11 1969-02-18 Siemens Ag Method and apparatus for overlay welding
US3493713A (en) * 1967-02-20 1970-02-03 Arcos Corp Electric arc overlay welding
US3573420A (en) * 1968-12-23 1971-04-06 Arcos Corp Process and apparatus for nonconsumable electrode overlay welding
US3673374A (en) * 1970-04-22 1972-06-27 Union Carbide Corp Surface metal welding process and apparatus

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1986704A (en) * 1933-03-14 1935-01-01 Bannister Bryant Protective coating for metals
US3310423A (en) * 1963-08-27 1967-03-21 Metco Inc Flame spraying employing laser heating
DE1295960B (en) 1965-02-22 1969-05-22 Gewerk Eisenhuette Westfalia Method and device for applying metallic coating materials to the surfaces of workpieces
DE2026007A1 (en) 1969-08-28 1971-03-18 American Optical Corp Method for producing layer bodies

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3139511A (en) * 1961-05-18 1964-06-30 Standard Pressed Steel Co Fusion cladding technique and product
US3185814A (en) * 1961-12-30 1965-05-25 Siemens Ag Method and apparatus for overlay welding
US3428774A (en) * 1964-06-11 1969-02-18 Siemens Ag Method and apparatus for overlay welding
US3296408A (en) * 1966-02-01 1967-01-03 R I Patents Inc Dual arc welding
US3493713A (en) * 1967-02-20 1970-02-03 Arcos Corp Electric arc overlay welding
US3573420A (en) * 1968-12-23 1971-04-06 Arcos Corp Process and apparatus for nonconsumable electrode overlay welding
US3673374A (en) * 1970-04-22 1972-06-27 Union Carbide Corp Surface metal welding process and apparatus

Cited By (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4015100A (en) * 1974-01-07 1977-03-29 Avco Everett Research Laboratory, Inc. Surface modification
US4125926A (en) * 1975-09-02 1978-11-21 Caterpillar Tractor Co. Method of making aluminum piston with reinforced piston ring groove
US4157923A (en) * 1976-09-13 1979-06-12 Ford Motor Company Surface alloying and heat treating processes
US4059876A (en) * 1976-11-03 1977-11-29 General Motors Corporation Method of alloying and forming a valve seat
US4322601A (en) * 1978-08-14 1982-03-30 Serlin Richard A Surface alloying method and apparatus using high energy beam
US4260095A (en) * 1978-08-18 1981-04-07 Smith Phillip H Method of manufacturing a clad product
US4239556A (en) * 1978-12-22 1980-12-16 General Electric Company Sensitized stainless steel having integral normalized surface region
US4323756A (en) * 1979-10-29 1982-04-06 United Technologies Corporation Method for fabricating articles by sequential layer deposition
US4348263A (en) * 1980-09-12 1982-09-07 Western Electric Company, Inc. Surface melting of a substrate prior to plating
US4495255A (en) * 1980-10-30 1985-01-22 At&T Technologies, Inc. Laser surface alloying
US4451299A (en) * 1982-09-22 1984-05-29 United Technologies Corporation High temperature coatings by surface melting
US4468552A (en) * 1982-09-29 1984-08-28 Advanced Technologies, Inc. Method of applying hard surfaces to gate valves and the like
US4644127A (en) * 1984-08-20 1987-02-17 Fiat Auto S.P.A. Method of carrying out a treatment on metal pieces with the addition of an added material and with the use of a power laser
US4743733A (en) * 1984-10-01 1988-05-10 General Electric Company Method and apparatus for repairing metal in an article
EP0176942B1 (en) 1984-10-01 1989-05-24 General Electric Company Method for repairing metal in an article
US4785775A (en) * 1984-12-20 1988-11-22 Sulzer Brothers Limited Wear layer for piston and cylinder of an internal combustion engine
US5084113A (en) * 1985-05-24 1992-01-28 Toyota Jidosha Kabushiki Kaisha Method of producing a buildup valve for use in internal combustion engines
US4725708A (en) * 1985-07-17 1988-02-16 Toyota Jidosha Kabushiki Kaisha Method for padding a copper type alloy material upon a base of aluminum type metal using laser beam oscillating transversely to its tracking direction
US4663513A (en) * 1985-11-26 1987-05-05 Spectra-Physics, Inc. Method and apparatus for monitoring laser processes
US4873416A (en) * 1987-08-27 1989-10-10 Rheinmetall Gmbh Method for the application and fastening of rotating bands on projectile bodies
US4803334A (en) * 1987-11-16 1989-02-07 Westinghouse Electric Corp. Method for laser beam welding metal matrix composite components
US4835357A (en) * 1988-06-20 1989-05-30 Williams International Corporation Sheet metal laser welding
US4926022A (en) * 1989-06-20 1990-05-15 Digital Equipment Corporation Laser reflow soldering process and bonded assembly formed thereby
DE3928092A1 (en) * 1989-08-25 1991-02-28 Mordike Barry Leslie Coating metal surfaces using laser-wire coating method - with wire electro-resistance preheated to improve flow capabilities and improve coating qualities
US5127364A (en) * 1989-12-18 1992-07-07 General Electric Company Apparatus for making A-15 type tape superconductors which includes means to melt a wire at its tip so a beam is formed and means for wiping the bead onto a continuous tape substrate
EP0698800A1 (en) 1994-08-25 1996-02-28 Fraunhofer-Gesellschaft Zur Förderung Der Angewandten Forschung E.V. Process for controlling the laserbeam intensity repartition for processing element surfaces
DE4430220A1 (en) * 1994-08-25 1996-02-29 Fraunhofer Ges Forschung Process for controlling the laser beam intensity distribution for the machining of component surfaces
DE4430220C2 (en) * 1994-08-25 1998-01-22 Fraunhofer Ges Forschung Method for controlling the laser beam intensity distribution on the surface of components to be processed
US5889254A (en) * 1995-11-22 1999-03-30 General Electric Company Method and apparatus for Nd: YAG hardsurfacing
US5759641A (en) * 1996-05-15 1998-06-02 Dimitrienko; Ludmila Nikolaevna Method of applying strengthening coatings to metallic or metal-containing surfaces
US5578227A (en) * 1996-11-22 1996-11-26 Rabinovich; Joshua E. Rapid prototyping system
US6144008A (en) * 1996-11-22 2000-11-07 Rabinovich; Joshua E. Rapid manufacturing system for metal, metal matrix composite materials and ceramics
US6146476A (en) * 1999-02-08 2000-11-14 Alvord-Polk, Inc. Laser-clad composite cutting tool and method
US6402438B1 (en) 1999-02-08 2002-06-11 Alvord-Polk, Inc. Composite Cutting Tool
US6441338B1 (en) 1999-04-19 2002-08-27 Joshua E. Rabinovich Rapid manufacturing of steel rule dies and other 3-dimensional products, apparatus, process and products
US20060163521A1 (en) * 2005-01-26 2006-07-27 Honeywell International, Inc. Solid-free-form fabrication of hot gas valve discs
US7509738B2 (en) * 2005-01-26 2009-03-31 Honeywell International, Inc. Solid-free-form fabrication of hot gas valve discs
US8586398B2 (en) 2008-01-18 2013-11-19 Miasole Sodium-incorporation in solar cell substrates and contacts
US8536054B2 (en) * 2008-01-18 2013-09-17 Miasole Laser polishing of a solar cell substrate
US20100255630A1 (en) * 2008-01-18 2010-10-07 Miasole Sodium-incorporation in solar cell substrates and contacts
US20100258982A1 (en) * 2008-01-18 2010-10-14 Miasole Laser polishing of a solar cell substrate
US8546172B2 (en) 2008-01-18 2013-10-01 Miasole Laser polishing of a back contact of a solar cell
US20090274923A1 (en) * 2008-03-04 2009-11-05 Kenneth Hall Tools Having Compacted Powder Metal Work Surfaces, And Method
US20110000953A1 (en) * 2008-03-07 2011-01-06 The Ohio State University Low-temperature spot impact welding driven without contact
US8084710B2 (en) * 2008-03-07 2011-12-27 The Ohio State University Low-temperature laser spot impact welding driven without contact
US20100155374A1 (en) * 2008-11-04 2010-06-24 Rabinovich Joshua E process for energy beam solid-state metallurgical bonding of wires having two or more flat surfaces
US8334475B2 (en) * 2008-11-04 2012-12-18 Rabinovich Joshua E Process for energy beam solid-state metallurgical bonding of wires having two or more flat surfaces
US20110106290A1 (en) * 2009-10-30 2011-05-05 Hoevel Simone Method of applying multiple materials with selective laser melting on a 3d article
US9901983B2 (en) * 2009-10-30 2018-02-27 Ansaldo Energia Ip Uk Limited Method of applying multiple materials with selective laser melting on a 3D article
US9168613B2 (en) 2010-10-22 2015-10-27 Paul T. Colby Vertical laser cladding system
US11898214B2 (en) 2012-09-06 2024-02-13 Etxe-Tar, S.A. Method and system for heat treating a workpiece
US10961597B2 (en) 2012-09-06 2021-03-30 Exteotar, S.A. Method and system for laser hardening of a surface of a workpiece
US10138528B2 (en) 2012-09-06 2018-11-27 Etxe-Tar, S.A. Method and system for laser hardening of a surface of a workpiece
US9289845B2 (en) 2012-11-07 2016-03-22 David S. Henn Metal deposition of exterior members in oil field tubulars
US20150343563A1 (en) * 2013-02-01 2015-12-03 Siemens Aktiengesellschaft Welding method having welding power depending upon thickness
US9228609B2 (en) 2013-08-16 2016-01-05 Caterpillar Inc. Laser cladding fabrication method
US9381594B2 (en) 2013-11-04 2016-07-05 Caterpillar Inc. Laser cladding with a laser scanning head
WO2015065655A1 (en) 2013-11-04 2015-05-07 Caterpillar Inc. Laser cladding with a laser scanning head
US9683466B2 (en) * 2014-06-30 2017-06-20 Mahle Metal Leve S/A Valve for internal combustion engines and method for obtaining a valve
US20150377089A1 (en) * 2014-06-30 2015-12-31 Mahle International Gmbh Valve for internal combustion engines and method for obtaining a valve
US20170239751A1 (en) * 2014-11-12 2017-08-24 Jiangsu University Laser thermal combination remanufacturing method for damaged metal part
US10391587B2 (en) * 2014-11-12 2019-08-27 Jiangsu University Laser thermal combination remanufacturing method for damaged metal part
US10864603B2 (en) 2015-03-17 2020-12-15 Ikergune A.I.E. Method and system for heat treatment of sheet metal
US20190126387A1 (en) * 2016-04-08 2019-05-02 Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E.V. Device and method for producing metallic components

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